Stedman's > equilibrium constantequilibrium constant
in the reaction A + B ⇄ C + D at equilibrium (no net change in concentrations of A, B, C, or D), the concentrations of the four components are related by the equation
Keq = [C][D]/[A][B];
Keq is the equilibrium constant If any component in the reaction has a multiplier (H
2 ⇄ 2H), that multiplier appears as an exponent in the calculation of
K (
Keq = [H]2/[H
2]). When this equation is applied to the ionization of a substance in solution,
Keq is called the dissociation constant (
Kd) and its negative logarithm (base 10) is the p
Kd.
See Also: Henderson-Hasselbalch equation, mass:action ratio